Electron and nuclear spin dynamics in antiferromagnetic molecular rings

Authors
Citation
F. Meier et D. Loss, Electron and nuclear spin dynamics in antiferromagnetic molecular rings, PHYS REV L, 86(23), 2001, pp. 5373-5376
Citations number
24
Categorie Soggetti
Physics
Journal title
PHYSICAL REVIEW LETTERS
ISSN journal
00319007 → ACNP
Volume
86
Issue
23
Year of publication
2001
Pages
5373 - 5376
Database
ISI
SICI code
0031-9007(20010604)86:23<5373:EANSDI>2.0.ZU;2-K
Abstract
We study theoretically the spin dynamics of antiferromagnetic molecular rin gs, such as the ferric wheel Fe-10. For a single nuclear or impurity spin c oupled to one of the electron spins of the ring,we calculate nuclear and el ectronic spin correlation functions and show that nuclear magnetic resonanc e (NMR) and electron spin resonance (ESR) techniques can be used to detect coherent tunneling of the Neel vector in these rings. The location of the N MR/ESR resonances gives the tunnel splitting and its linewidth an upper bou nd on the decoherence rate of the electron spin dynamics. We illustrate the experimental feasibility of our proposal with estimates for Fe-10 molecule s.