DETERMINATION OF THE MIXING POTENTIAL-V BETWEEN THE BIPOLARON AND THEITINERANT-ELECTRON AND POSSIBLE 2-COMPONENT INTERACTION SUPERCONDUCTIVITY BASED ON A LOW N(E-F) FOR DOPED FULLERENES
J. Lu et al., DETERMINATION OF THE MIXING POTENTIAL-V BETWEEN THE BIPOLARON AND THEITINERANT-ELECTRON AND POSSIBLE 2-COMPONENT INTERACTION SUPERCONDUCTIVITY BASED ON A LOW N(E-F) FOR DOPED FULLERENES, Physica. C, Superconductivity, 279(3-4), 1997, pp. 209-218
A mixing potential V=0.23 eV was obtained in the normal state within t
he negative U Anderson-lattice model (two-component model) if the addi
tional spectral weight in the band gap observed on K3C60 is attributed
to the additional bipolaron state. The superconducting transition tem
perature T-c, penetration depth lambda, coherent length xi, thermodyna
mic critical field H-c, specific heat jump Delta C/T-c and isotope eff
ect exponent cu can be well reproduced within the same model based on
a low density of states at the Fermi level, N(E-F)approximate to 3 sta
tes/eV C-60 spin, which is another general observation when using phot
oemission spectroscopy, with a mixing potential V=0.075-0.12 eV. The s
maller discrepancy in V seems to support the two-component interaction
superconductivity for doped fullerenes. (C) 1997 Elsevier Science B.V
.