Crystal structure of calcium [aqua(nitrilotriacetatocobaltate(II)] tetrahydrate, Ca[Co(Nta)(H2O)](2) center dot 4H(2)O

Crystals of Ca[Co-II(Nta)](2). 6H(2)O (I), where Nta(3-) is a nitrilotriace tate ion, were synthesized and studied using X-ray diffraction analysis. Th ey were found to be monoclinic: a = 6.991(1), b = 10.03 1(1), c = 16.238(3) Angstrom, beta = 98.50(1)degrees, V= 1126.2(3) Angstrom (3), space group P 2(1)/n, Z = 2, R-1 = 0.0241, wR(2) = 0.0636, GOOF = 1.050 (for 3132 reflect ions with I > 2 sigma (I)). Structure I is composed of ([Co(Nta)(H2O)](-))( I infinity), anion chains united by Ca2+ cations into a three-dimensional f ramework. The coordination polyhedra of Co and Ca atoms are distorted octah edra. The Co(II) atom environment includes atoms N(1), O(1), O(3), and O(5) of one Nta(3-) ligand, a carbonyl O(2)' atom of the neighboring anion frag ment, and an O(w1) atom of the water molecule. The shortest bond is formed by the Co atom with the bridging O(2)' atom in trans-position relative to a tom N(1). The Co-O(2)' distance (2.029 Angstrom) is noticeably shorter than the other bond lengths, Co-O(Nta) (2.069-2.103 Angstrom), Co-O(w1), and Co -N(1) (2.155 and 2.177 Angstrom, respectively). Cations Ca2+ are located in the inversion centers and involve in their coordination atoms O(4), O(6), O(w2), and the oxygen atoms symmetrically bond to them and arranged at 2.27 1(1), 2.420(1), and 2.351(2) A, respectively. The structural formula of the title compound is {Ca(H2O)(2)[Co(Nta)(H2O)](2)}(3 infinity) . 2H(2)O.