Iodination of B12H11OC(O)CH32-, B12H11OH2-, and B12H11SCN2-

Authors
Gorobinskii, LV Chernyavskii, AS Solntsev, KA Kuznetsov, NT
Citation
Lv. Gorobinskii et al., Iodination of B12H11OC(O)CH32-, B12H11OH2-, and B12H11SCN2-, RUSS J C CH, 27(3), 2001, pp. 147-149
Citations number
10
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
RUSSIAN JOURNAL OF COORDINATION CHEMISTRY
ISSN journal
10703284 → ACNP
Volume
27
Issue
3
Year of publication
2001
Pages
147 - 149
Database
ISI
SICI code
1070-3284(200103)27:3<147:IOBBAB>2.0.ZU;2-D
Abstract
Reactions of iodination of monosubstituted derivatives of B12H11X2- anion ( X = OC(O)CH3, OH, SCN) were studied. The reactions were shown to proceed sm oothly to give B12H10(OC(O)CH3)](2-) ((carboxy)(iodo) [decahydro[l(h) 1551- Delta (20)-closo] dodecaborate(2-)] anion), B12H10(OH)](2-) ((hydroxo)(iodo ) [decahydro[I-h 1551-Delta (20)-closo]dodecaborate(2-)] anion), and B12H10 (SCN)](2-) ((thiocyanato)(iodo)[decahydro[I-h 1551-Delta (20)-closo]dodecab orate(2-)] anion) in high yields, irrespective of the solvent used (benzene , H2O-ROH, where R = C2H5, CH2CH2CH3).(1)