NMR study of reactions between Pd, Ru, and Rh nitrite complexes with sulfamic acid

Authors
Belyaev, AV Emel'yanov, VA Khranenko, SP Fedotov, MA
Citation
Av. Belyaev et al., NMR study of reactions between Pd, Ru, and Rh nitrite complexes with sulfamic acid, RUSS J C CH, 27(3), 2001, pp. 184-194
Citations number
20
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
RUSSIAN JOURNAL OF COORDINATION CHEMISTRY
ISSN journal
10703284 → ACNP
Volume
27
Issue
3
Year of publication
2001
Pages
184 - 194
Database
ISI
SICI code
1070-3284(200103)27:3<184:NSORBP>2.0.ZU;2-V
Abstract
Reactions of nitrite complexes of Pd, Ru, and Rh with sulfamic acid were st udied by the N-14,N-15, and O-17 NMR method. Chemical shifts were assigned, and the predominant forms of the complexes were established. The reaction products at room temperature are cis-nitroaqua complexes. Coordination of t he sulfamate ion upon storage for a long time or on heating was detected.