Silver intercalation in PbS1.18(TiS2)(n), n=1, 2, misfit layer compounds

Authors
Titov, AN Bryntse, I Titova, SG Toporova, NV
Citation
An. Titov et al., Silver intercalation in PbS1.18(TiS2)(n), n=1, 2, misfit layer compounds, SOL ST ION, 140(3-4), 2001, pp. 293-300
Citations number
17
Categorie Soggetti
Apllied Physucs/Condensed Matter/Materiales Science
Journal title
SOLID STATE IONICS
ISSN journal
01672738 → ACNP
Volume
140
Issue
3-4
Year of publication
2001
Pages
293 - 300
Database
ISI
SICI code
0167-2738(200104)140:3-4<293:SIIPN2>2.0.ZU;2-N
Abstract
The reaction between metallic Ag and PbS1.18(TiS2)(n), n=l, 2, misfit layer compounds has been investigated by electrochemical technique, X-ray powder analysis and transmission electron microscopy. It was found that silver in tercalation is possible only in the compound with n = 2. The thermodynamic behavior and location of phase boundaries were studied in the temperature r ange 400-650 K. DC-conductivity and magnetic-susceptibility measurements we re performed, and the data can be interpreted as an appearance of small pol arons during silver insertion. (C) 2001 Elsevier Science B.V. All rights re served.