Thermal and complex impedance analysis of amorphous and crystalline lithium salt mixtures

Authors
Dillon, REA Shriver, DF
Citation
Rea. Dillon et Df. Shriver, Thermal and complex impedance analysis of amorphous and crystalline lithium salt mixtures, SOL ST ION, 140(3-4), 2001, pp. 375-380
Citations number
30
Categorie Soggetti
Apllied Physucs/Condensed Matter/Materiales Science
Journal title
SOLID STATE IONICS
ISSN journal
01672738 → ACNP
Volume
140
Issue
3-4
Year of publication
2001
Pages
375 - 380
Database
ISI
SICI code
0167-2738(200104)140:3-4<375:TACIAO>2.0.ZU;2-N
Abstract
Amorphous electrolytes consisting of the lithium salts, Li[R-NSO2CF3] were prepared and the attendant low ionic conductivities of the lithium salt mix tures (similar to 1 X 10(-6) S cm(-1) at room temperature) are attributed t o high glass transition temperatures. An example is the novel amorphous sal t, Li[18-C-6NSO(2)CF(3)] which produces an amorphous salt mixture with Li[N (SO2CF3)(2)] (LiTFSI). (C) 2001 Elsevier Science B.V. All rights reserved.