Diastereoselective synthesis of homopropargylic alcohols on solid support

Authors
Cossy, J Defosseux, M Meyer, C
Citation
J. Cossy et al., Diastereoselective synthesis of homopropargylic alcohols on solid support, SYNLETT, (6), 2001, pp. 815-817
Citations number
21
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
SYNLETT
ISSN journal
09365214 → ACNP
Issue
6
Year of publication
2001
Pages
815 - 817
Database
ISI
SICI code
0936-5214(200106):6<815:DSOHAO>2.0.ZU;2-R
Abstract
The reaction of allenic stannanes immobilized on carboxypolystyrene with al dehydes. promoted by BF3. OEt2 or mediated by InBr3. affords after cleavage from the resin, the corresponding homopropargylic alcohols in high purity, free of tin containing byproducts.