Silicone as a new class of organosilicon reagent for the palladium-catalyzed cross-coupling reaction

Authors
Mori, A Suguro, M
Citation
A. Mori et M. Suguro, Silicone as a new class of organosilicon reagent for the palladium-catalyzed cross-coupling reaction, SYNLETT, (6), 2001, pp. 845-847
Citations number
19
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
SYNLETT
ISSN journal
09365214 → ACNP
Issue
6
Year of publication
2001
Pages
845 - 847
Database
ISI
SICI code
0936-5214(200106):6<845:SAANCO>2.0.ZU;2-E
Abstract
Silicone, polyorganosiloxane, serves as an organosilicon reagent for pallad ium-catalyzed cross-coupling reactions. Treatment of polymethylphenylsiloxa ne, poly(alkenyl)methylsiloxane, or cyclic oligosiloxanes with various aryl iodides in the presence of silver(I) oxide or tetrabutylammonium fluoride and a catalytic amount of Pd(0) affords the corresponding coupling product in a good to excellent yield.