A series of confined swell and hydraulic conductivity tests were condu
cted on a needle-punched geosynthetic clay liner (GCL) with water as t
he hydrating medium and reference permeant. Increases in the static co
nfining stress and the needle-punching both restricted GCL swell and c
ontributed to lower bulk GCL void ratios and hence significantly lower
hydraulic conductivity values. A well defined linear-log relationship
is found between the bulk void ratio and hydraulic conductivity. The
number of pore volumes of permeant flow and consequently the level of
chemical equilibrium is shown to have a significant effect on the hydr
aulic conductivity. It is shown that there is a decrease in hydraulic
conductivity for small amounts of permeant flow for all ethanol/water
mixtures examined. At or near chemical equilibrium, low concentration
mixtures (25 and 50% ethanol) continued to produce relative decreases
in GCL hydraulic conductivity due to the increased viscosity of the pe
rmeant; however, highly concentrated mixtures (75 and 100% ethanol) pr
oduced relative increases in GCL hydraulic conductivity arising from d
ouble layer contraction. The implications are discussed.