A. Dhawan et al., Study of oxidation behaviour of Zr-based bulk amorphous alloy Zr65CU17.5Ni10Al7.5 by thermogravimetric analyser, B MATER SCI, 24(3), 2001, pp. 281-283
The oxidation behaviour of Zr-based bulk amorphous alloy Zr65Cu17.5Ni10Al7.
5 has been studied in air environment at various temperatures in the temper
ature range 591-684 K using a thermogravimetric analyser (TGA), The oxidati
on kinetics of the alloy in the amorphous phase obeys the parabolic rate la
w for oxidation in the temperature range 591-664 K, The values of the activ
ation energy and pre-factor as calculated From the Arrhenius temperature de
pendence of the rate constants have been found to be 1(.)80 eV and 2(.)12 x
10(9) g(.)cm(-2) sec(-1/2), respectively.