Subsystem dynamics in mixed quantum-classical systems

Citation
M. Toutounji et R. Kapral, Subsystem dynamics in mixed quantum-classical systems, CHEM PHYS, 268(1-3), 2001, pp. 79-89
Citations number
77
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
CHEMICAL PHYSICS
ISSN journal
03010104 → ACNP
Volume
268
Issue
1-3
Year of publication
2001
Pages
79 - 89
Database
ISI
SICI code
0301-0104(20010615)268:1-3<79:SDIMQS>2.0.ZU;2-0
Abstract
Starting with the mixed quantum-classical Liouville equation, projection op erator methods are used to derive an equation of motion for a quantum subsy stem dissipatively interacting with a classical bath. The resulting general ized master equation is reduced to the Lindblad equation after making a Mar kovian approximation in the weak coupling limit. The bath subsystem dynamic s is studied from a similar perspective. For situations where the classical subsystem consists of few degrees of freedom, or one is interested in the nature of the modifications of its dynamics as a result of coupling to a la rge, rapidly relaxing quantum bath, a classical analog of the Lindblad equa tion is derived and discussed. (C) 2001 Elsevier Science B.V. All rights re served.