Soliton model for proton conductivity in Langmuir films

Citation
D. Bazeia et al., Soliton model for proton conductivity in Langmuir films, CHEM P LETT, 340(3-4), 2001, pp. 205-210
Citations number
25
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
CHEMICAL PHYSICS LETTERS
ISSN journal
00092614 → ACNP
Volume
340
Issue
3-4
Year of publication
2001
Pages
205 - 210
Database
ISI
SICI code
0009-2614(20010601)340:3-4<205:SMFPCI>2.0.ZU;2-V
Abstract
A soliton model for proton conductivity in Langmuir films is presented. The model contains three real scalar fields describing the hydrogen involved i n the conduction, the hydrophilic head of the Langmuir film, and the water. Soliton solutions that describe proton motion along the hydrogen bonds are found. Under compression of the film, the distance between the minima of t he proton potential and the strength of the hydrogen bonds between the film molecule and the water are changed. Such changes increase the probability of soliton creation. The model. presented allows proton conductivity data i n Langmuir films to be explained. (C) 2001 Published by Elsevier Science B. V.