A bis(carboxamido-N)diisocyanidobis(sulfenato-S)cobalt(III) complex, modelfor the post-translational oxygenation of nitrile hydratase thiolato ligands

Authors
Heinrich, L Li, Y Vaissermann, J Chottard, JC
Citation
L. Heinrich et al., A bis(carboxamido-N)diisocyanidobis(sulfenato-S)cobalt(III) complex, modelfor the post-translational oxygenation of nitrile hydratase thiolato ligands, EUR J INORG, (6), 2001, pp. 1407-1409
Citations number
15
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY
ISSN journal
14341948 → ACNP
Issue
6
Year of publication
2001
Pages
1407 - 1409
Database
ISI
SICI code
1434-1948(200106):6<1407:ABCM>2.0.ZU;2-6
Abstract
A square-planar cobalt(III) complex with an N2S2 bis(carbox-amido-N)dithiol ato tetradentate ligand was oxygenated by H2O2-urea, after axial coordinati on of tert-butyl isocyanide, to the first bis(carboxamido-N) bis(sulfenato- S)cobalt(III) complex.