CsPd2Cl5 - A new structural type containing (1)(infinity)[(PdCl3/2Cl)(2)(-)] chains

Authors
Schupp, B Keller, HL
Citation
B. Schupp et Hl. Keller, CsPd2Cl5 - A new structural type containing (1)(infinity)[(PdCl3/2Cl)(2)(-)] chains, EUR J INORG, (6), 2001, pp. 1431-1435
Citations number
21
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY
ISSN journal
14341948 → ACNP
Issue
6
Year of publication
2001
Pages
1431 - 1435
Database
ISI
SICI code
1434-1948(200106):6<1431:C-ANST>2.0.ZU;2-W
Abstract
CsPd2Cl5 has been obtained by hydrothermal reaction of cesium chloride and palladium chloride in a 1:2 ratio in quartz glass ampoules at 150 degreesC. Its crystal structure has been determined by single-crystal X-ray diffract ion analysis [Pnma, Z = 4, alpha = 15.725(3) Angstrom, b = 10.526(2) Angstr om, c = 5.275(1) Angstrom]. CsPd2Cl5 represents the first example of a new structural type made up of infinite (1)(infinity)[(PdCl3/2Cl)(2)(-)] chains , in which PdCl4 units are connected through their edges as well as their v ertices.