New enantioselective synthesis of (10R,11S)-(+)-juvenile hormones I and II

Authors
Citation
T. Okochi et K. Mori, New enantioselective synthesis of (10R,11S)-(+)-juvenile hormones I and II, EUR J ORG C, (11), 2001, pp. 2145-2150
Citations number
23
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
ISSN journal
1434193X → ACNP
Issue
11
Year of publication
2001
Pages
2145 - 2150
Database
ISI
SICI code
1434-193X(200106):11<2145:NESO(H>2.0.ZU;2-B
Abstract
The (10R,11S)-(+)-juvenile hormones I (1) and II (2) were synthesized by Sh arpless asymmetric dihydroxylations of methyl (2E,6E, 10E)-7-ethyl-3, 11-di methyl-2,6,10-tridecatrienoate (4) and methyl (2E,6E,10E)-3,7,11-trimethyl- 2,6,10-tridenoate (5), respectively, as the key steps.