We report on the use of in situ scanning tunneling microscopy to study As/P
exchange on InP(001) surfaces by molecular beam epitaxy. Results demonstra
te that the exchange process can be controlled to selectively produce eithe
r quantum wires or quantum dots. 15 nm wide self-assembled nanowires are ob
served, and they are elongated along the dimer row direction of the InP(001
)-2 X 4 surface with a length of over 1 mum and flat top 2 X 4 surfaces. In
addition, when the nanowires are annealed with no arsenic overpressure, th
e surface reconstruction transforms from 2 X 4 to 4 X 2 and the nanowires t
ransform into dots with a rectangular base and flat top. (C) 2001 American
Institute of Physics.