Resistivity and Hall effect measurements were made on single crystals
of NiS2 and Ni(S0.9Se0.1)(2) under high pressure in a temperature rang
e between 4.2 and 300 K. NiS2 and Ni(S0.9Se0.1)(2) show insulator-meta
l transitions. Anomalous behavior of resistivity corresponding to a pa
ra-antiferromagnetic transition was found in the metallic phase. The H
all coefficient and the Hall mobility decrease with increasing pressur
e. It is suggested that the electronic structure of Ni(S1-xSex)(2) in
the insulating phase is modified toward the phase boundary of the insu
lator-metal transition.