Hl. Tyan et al., Effect of montmorillonite on thermal and moisture absorption properties ofpolyimide of different chemical structures, J APPL POLY, 81(7), 2001, pp. 1742-1747
The thermal properties and the moisture absorption of three types of polyim
ide/montmorillonite nanocomposite were investigated: 3,3 ' ,4,4 ' -biphenyl
tetracarboxylic dianhydride-4,4 ' -oxydianiline (BPDA-ODA); pyromellitic d
ianhydride-ODA (PMDA-ODA); and 3,3 ' ,4,' -benzophenone tetracarboxylic dia
nhydride-ODA (BTDA-ODA). The inhibition effect on in-plane coefficients of
thermal expansion (CTE) and moisture absorption of these polyimide nanocomp
osites by layered silicates from montmorillonite was found to decrease with
the crystallinity in the pristine polyimides. The largest reduction, 30% i
n in-plane CTE occurred in the case of amorphous BTDA-ODA containing 5 wt %
montmorillonite as compared with that of pure BTDA-ODA, while the reductio
n in in-plane CTE was 20% for the case of semicrystalline BPDA-ODA. The max
imum reduction in moisture absorption, 43%, also took place for the case of
3/97 ODA-Mont/BTDA-ODA as compared with that of pure BTDA-ODA, whereas the
semicrystalline 1/99 PPD-Mont/BPDA-ODA showed a 30% reduction as compared
with that of pure BPDA-ODA. (C) 2001 John Wiley & Sons, Inc.