Some novel cross-linkable fluorinated poly(arylene ether sulfides) (FPAFSI)
mere synthesized for use in optical waveguide applications. The materials
have high thermal stability, high optical transparency in the infrared comm
unication region, and much less birefringence than other thermally stable f
luorinated polyimides. The refractive index of FPAESI after storage at 100
degreesC for 1000 h remains almost constant, demonstrating their thermal st
ability. Furthermore, the refractive index of the material can be easily co
ntrolled by changing the fluorine content of the materials. The propagation
loss of channel waveguides, which were fabricated using reactive ion etchi
ng was less than 0.42 dB/cm and 0.4 dB/cm at the wavelength of 1.55 mum for
TE and TM polarizations, respectively.