A cryospectroscopic study of the oligomers of deuterium chloride in liquidargon, liquid krypton and in liquid nitrogen

Authors
Herrebout, WA Van Gils, J van der Veken, BJ
Citation
Wa. Herrebout et al., A cryospectroscopic study of the oligomers of deuterium chloride in liquidargon, liquid krypton and in liquid nitrogen, J MOL STRUC, 563, 2001, pp. 249-255
Citations number
18
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
JOURNAL OF MOLECULAR STRUCTURE
ISSN journal
00222860 → ACNP
Volume
563
Year of publication
2001
Pages
249 - 255
Database
ISI
SICI code
0022-2860(20010528)563:<249:ACSOTO>2.0.ZU;2-A
Abstract
The infrared spectra of HCl and DCl dissolved in liquid argon (94-148 K) in liquid krypton (117-167 K) and in liquid nitrogen (94-148 K) with mole fra ctions varying between 0.5 X 10(-4) and 2.5 X 10(-3) are discussed. In all solutions, bands proving the existence of oligomeric species (DCl)(x) were observed. Analysis of the spectra shows that these bands must be assigned t o dimeric, trimeric and tetrameric species. (C) 2001 Elsevier Science B.V. All rights reserved.