Citation
E. Akalin et S. Akyuz, Experimental and theoretical study of the vibrational spectra of paraphenylenediamine transition metal (II) complexes, J MOL STRUC, 563, 2001, pp. 579-586
Citations number
13
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
JOURNAL OF MOLECULAR STRUCTURE
ISSN journal
00222860
→ ACNP
Volume
563
Year of publication
2001
Pages
579 - 586
Database
ISI
SICI code
0022-2860(20010528)563:<579:EATSOT>2.0.ZU;2-E
Abstract
The effect of coordination of p-phenylenediamine molecule (PPD) to a transi
tion metal has been investigated by making use of the normal coordinate ana
lysis. The reliable force field of coordinated PPD have been determined by
refinement of the free PPD in order to fit the experimental wavenumbers of
transition metal (II) PPD complexes. Additionally, CdI2(PPD) and MnCl2(PPD)
complexes have been prepared and their vibrational assignment is provided
based on this calculation. (C) 2001 Elsevier Science B.V. All rights reserv
ed.