The absolute cross section for photoionization of CO+ ions leading to forma
tion of longlived metastable CO2+ ions has been measured from the threshold
at 27.3 eV to 50 eV utilizing a merged ion-photon beam set-up with synchro
tron radiation from an undulator. The continuum cross section reaches a val
ue of 2.5(4) Mb near threshold and decreases slowly with increasing photon
energy. Superimposed on this continuum discrete structures are observed, wh
ich can be assigned to CO+(4 sigma5 sigma (3)Sigma (+)(nu = 0))nl lambda Ry
dberg series with n greater than or equal to 5.