The influence of ligand states on the orbital magnetism of a 3d atom in a f
erromagnetic compound has been studied using an ab initio technique. It is
shown, using VAu4, MnAu4 and VPt3 as examples, that the large spin-orbit co
upling of the 5d atom is responsible for the reversal of the coupling betwe
en the V(Mn) spin and orbital moments with respect to that for similar comp
ounds. The VAu4 compound has a large magneto-crystalline anisotropy (MCA) a
nd the spin-up states are completely occupied, which makes its MCA proporti
onal to the orbital moment anisotropy as stated by Bruno's perturbative for
mula (Bruno P 1989 Phys, Rev. B 39 865). For the latter compound it is also
shown that a partial substitution of copper for gold decreases the vanadiu
m orbital moment and hence the MCA. The ligand state effects on the orbital
moment together with this alloying procedure may initiate a new approach i
n the search for ultra-soft magnetic materials.