E. Vogli et al., Conversion of oak to cellular silicon carbide ceramic by gas-phase reaction with silicon monoxide, J AM CERAM, 84(6), 2001, pp. 1236-1240
Oak has been converted to a porous biocarbon template by annealing in an in
ert atmosphere above 800 degreesC, Subsequent infiltration with gaseous SiO
at 1550-1600 degreesC under flowing argon of atmospheric pressure finally
resulted in the formation of a porous, cellular beta -SiC ceramic. The conv
ersion retains the biomorphic cellular morphology of oak tissue. While pore
s in the cell walls with a diameter less than similar to1 mum vanished, two
distinct pore channel maxima representing tracheidal cells and large vesse
ls remained in the SiC ceramic. Depending on the cellular morphology of dif
ferent kinds of wood, e,g,, strut thickness and pore size distribution, gas
-phase conversion to single-phase beta -SiC can be used to manufacture cell
ular ceramics with a wide range of pore channel diameters.