This work is devoted to the theoretical understanding of the microstructure
and thermal conductivity relationships of compacted ceramic powders in the
initial, nondensifying stage of sintering, A model based on surface diffus
ion of vacancies for the growth of the neck between particles is combined w
ith numerical fully three-dimensional code calculations, which solve for th
e effective heat conductivity coefficient of lightly sintered particles. Th
e predictions of the model are in agreement with experimental observations.
The approach presented can be applied to solve a series of related problem
s, like dielectric properties, with arbitrary microstructure and multicompo
nent composite of the powders.