The phenolic beta -diketones I prepared by modified Baker-Venkataraman rear
rangement were converted to benzodiazepine derivatives II by treatment with
o-phenylenediamine. Coupling of benzodiazepine derivatives II with acetobr
omo sugars in presence of mercuric cyanide and nitromethane gave acetylated
sugar derivatives of benzodiazepines III. The nucleosides IV were obtained
by the deacetylation of compounds III. Structures of all intermediates and
final products were confirmed with the help of modern spectroscopic method
s.