Liquid crystal elastomer balloons

Citation
H. Schuring et al., Liquid crystal elastomer balloons, MACROMOLEC, 34(12), 2001, pp. 3962-3972
Citations number
32
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
MACROMOLECULES
ISSN journal
00249297 → ACNP
Volume
34
Issue
12
Year of publication
2001
Pages
3962 - 3972
Database
ISI
SICI code
0024-9297(20010605)34:12<3962:LCEB>2.0.ZU;2-8
Abstract
We describe a setup for mechanical measurements of smectic liquid crystal e lastomers and study two materials with different network topologies. The el astic response of macroscopically oriented smectic elastomers to a two-dime nsionally isotropic stress in the film plane is measured. The experimental method is based upon the measurement of the inner excess pressure of elasto mer balloons, produced by inflation of thin freely suspended films of the s mectic material to spherical shape and subsequent photo-cross-linking. We d iscuss the effects of entropic rubber elasticity and smectic layer compress ion in the experiment and analyze influences of the network topology (2D or 3D) on the elastic behavior.