S. Terashima et al., Improvement in thermal reliability of a flip chip interconnection system joined by Pb-free solder and Au bumps, MATER TRANS, 42(5), 2001, pp. 803-808
The failure mechanism and improvement in the thermal reliability were studi
ed of a new dip chip interconnection system using Au bumps on Si chips and
Sn bumps on substrates. The thermal reliability of this hip chip depended o
n the diffusion behaviour at the Au/Sn bonded interface. Kirkendall voids,
which were formed at the Au/Sn bonded interface, induced cracks and impaire
d the reliability. By the addition of Ag into the Sn bumps, the reliability
was improved, due to the formation of an Ag concentrated layer at the Au/S
n bonded interface which acted as a barrier to Au-Sn further interdiffusion
and suppressed the Kirkendall voiding. The AuSn phase grew faster than the
other Au-Sn intermetallic compounds did at the Au/Sn bonded interface afte
r annealing. Activation energy for AuSn growth was 29.3 kJmol(-1).