UV laser-induced photolysis of diethyl selenium and diethyl tellurium: extrusion of selenium and tellurium via molecular elimination of ethene

Authors
Pola, J Ouchi, A
Citation
J. Pola et A. Ouchi, UV laser-induced photolysis of diethyl selenium and diethyl tellurium: extrusion of selenium and tellurium via molecular elimination of ethene, J ORGMET CH, 629(1-2), 2001, pp. 93-96
Citations number
32
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
JOURNAL OF ORGANOMETALLIC CHEMISTRY
ISSN journal
0022328X → ACNP
Volume
629
Issue
1-2
Year of publication
2001
Pages
93 - 96
Database
ISI
SICI code
0022-328X(20010601)629:1-2<93:ULPODS>2.0.ZU;2-V
Abstract
KrF laser-induced photolysis of gaseous (C2H5)(2)M (M = Se, Te) compounds i s shown to be a one-photon process controlled by the cleavage of both C-M b onds. It is dominated by the molecular elimination of ethene and yields ele mental selenium and tellurium. (C) 2001 Elsevier Science B.V. All rights re served.