Synthesis of diterpenoid indole derivatives via tethered chromium alkynylaminocarbenes

Authors
Woodgate, PD Sutherland, HS
Citation
Pd. Woodgate et Hs. Sutherland, Synthesis of diterpenoid indole derivatives via tethered chromium alkynylaminocarbenes, J ORGMET CH, 629(1-2), 2001, pp. 131-144
Citations number
24
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
JOURNAL OF ORGANOMETALLIC CHEMISTRY
ISSN journal
0022328X → ACNP
Volume
629
Issue
1-2
Year of publication
2001
Pages
131 - 144
Database
ISI
SICI code
0022-328X(20010601)629:1-2<131:SODIDV>2.0.ZU;2-V
Abstract
Thermolysis of podocarpane-tethered chromiumalkynylaminocarbenes gives indo le derivatives in moderate yields. (Arylalkynyl)aminocarbenes could not be isolated. Ester derivatives were formed due to trapping of the intermediate ketene in situ with butan-1-ol. (C) 2001 Elsevier Science B.V. All rights reserved.