Solid-state bilayer formation from a dialkyl-substituted lariat ether thatforms stable vesicles in aqueous suspension

Authors
De Wall, SL Barbour, LJ Gokel, GW
Citation
Sl. De Wall et al., Solid-state bilayer formation from a dialkyl-substituted lariat ether thatforms stable vesicles in aqueous suspension, J PHYS ORG, 14(7), 2001, pp. 383-391
Citations number
30
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
JOURNAL OF PHYSICAL ORGANIC CHEMISTRY
ISSN journal
08943230 → ACNP
Volume
14
Issue
7
Year of publication
2001
Pages
383 - 391
Database
ISI
SICI code
0894-3230(200107)14:7<383:SBFFAD>2.0.ZU;2-J
Abstract
Previously established aggregate formation by alkyl-substituted crown ether s is considered with respect to the solid state structure of N,N-didodecyld iaza- 18-crown-6 (7), which was determined as its NaI complex (7 . NaI .H2O ). The complex forms a bilayer structure that was used as a benchmark for u nderstanding the formation of aggregates and their inclusion volumes. Copyr ight (C) 2001 John Wiley & Sons, Ltd.