Optical properties of chromium(III) in (MIn)-In-I(MoO4)(2) hosts, where M-I = Li, Na, K, Rb, Cs

Authors
Hermanowicz, K Hanuza, J Maczka, M Deren, PJ Mugenski, E Drulis, H Sokolska, I Sokolnicki, J
Citation
K. Hermanowicz et al., Optical properties of chromium(III) in (MIn)-In-I(MoO4)(2) hosts, where M-I = Li, Na, K, Rb, Cs, J PHYS-COND, 13(25), 2001, pp. 5807-5816
Citations number
33
Categorie Soggetti
Apllied Physucs/Condensed Matter/Materiales Science
Journal title
JOURNAL OF PHYSICS-CONDENSED MATTER
ISSN journal
09538984 → ACNP
Volume
13
Issue
25
Year of publication
2001
Pages
5807 - 5816
Database
ISI
SICI code
0953-8984(20010625)13:25<5807:OPOCI(>2.0.ZU;2-R
Abstract
Electron absorption, excitation and emission as well as electron spin-reson ance spectra were measured for orthorhombic (K, Rb, Cs) and monoclinic (Li, Na) (MCrxIn1-x)-Cr-I (MoO4)(2) (x = 0 5-2%, M-I = Li, Na, K, Rb, Cs) in th e temperature range 5-300 K. The local structure of the Cr3+ ions is discus sed on the basis of spectroscopic results and the crystal-field parameters are derived for all of the materials. The possible application of the compo unds studied as laser materials is discussed.