Photoswitched singlet energy transfer in a porphyrin-spiropyran dyad

A photochromic nitrospiropyran moiety (Sp) has been covalently linked to a zinc (Pz,) and to a free-base (P-H2) porphyrin. In the resulting dyads (P-Z n-Sp(c) and P-H2-Sp(c)), the porphyrin first excited singlet states are unp erturbed by the closed form of the attached spiropyran. Excitation of the s piropyran moiety of either dyad in the near-UV region results in ring openi ng to a merocyanine form (P-Sp,) that absorbs at 600 nm. The open form re-c loses thermally in 2-methyltetrahydrofuran with a time constant of 20 s, or following irradiation into the 600 nm band. Excitation of the zinc porphyr in moiety in the merocyanine form of the dyad yields P-1(Zn)-Sp(o). The lif etime of the zinc porphyrin excited state is reduced from its usual value o f 1.8 ns to 130 ps by singlet-singlet energy transfer to the merocyanine mo iety to give P-Zn-(1)Sp(o). The quantum yield of energy transfer is 0.93. Q uenching is also observed in the free base dyad, where P-1(H2)-Sp(o) and P- H2-(1)Sp(o) exchange singlet excitation energy. This photoswitchable quench ing phenomenon provides light-activated control of the porphyrin excited st ates, and consequently control of any subsequent energy or electron-transfe r processes that might be initiated by these excited states in more complex molecular photonic or optoelectronic devices.