Am. Prokhorov et al., Complex borides with a ferromagnetic component: Development of the problemof magnetic superconductors, MAT RES INN, 5(1), 2001, pp. 15-20
Superconductors with a ferromagnet as one of the principal components are c
onsidered. A group of new stable superconductors (of the Y-Ni-B system) con
taining a ferromagnetic component up to 50% at. is found out as well. The Y
Ni1.9B1.2 phase is revealed to have the highest critical parameters among t
he known superconductors with a ferromagnetic component (T-c similar to 13,
5 K, DeltaT(c) similar to 0,6 K, J(c) - 5.10(4) A/cm(2), H-c2(0) up to 30 k
Oe). The model of its crystal structure is proposed. The YNi1.9B1.2 superco
nductor is characterized by an anomalous position of the H-c2(T) curve (the
positive convexity within 9.5-13.5 K). In a normal state, it is characteri
sed by an anomalous dependence of magnetic susceptibility on the temperatur
e and magnetic field, i.e. magnetic susceptibility chi shows no changes wit
h increasing temperature (within 15-273 K) in a fixed magnetic field and de
creases with increasing magnetic field from 0.214 to 4.28 kOe at a fixed te
mperature. The anomalous position of the curve can be described within the
WHH theory in the Fulde and Maki approximation, the positive convexity of t
he H-c2(T) curve being attributed to anomalous magnetic properties of the Y
Ni1.9B1.2 compound in a normal state. The coexistence of super conductivity
with antiferromagnetism is assumed in the analyzed compound.