Nonequilibrium heating occurs in a metallic substrate as the heating time a
pproaches the electron-phonon energy relaxation time. In this case the Four
ier heating model fails to predict the correct temperature rise in the surf
ace vicinity of the substrate. Consequently, the heating process needs to b
e examined at the microscopic level. In this study, laser picoseconds pulse
heating of gold is considered. The governing transport equation is derived
introducing an electron kinetic theory approach. The resulting high-order
differential equation describing the energy transport is decomposed into tw
o differential equations similar to those in the two-equation model. The pr
edictions of the electron kinetic theory approach are compared with the two
-equation model results for different values of the thermophysical properti
es of the substrate. It is found that for particular values of mean-free pa
th and the fraction of excess electron energy transfer to lattice site, bot
h predictions are identical. Moreover, the material response to heating pul
se is very sensitive as the values of the thermophysical properties of the
substrate change.