Electrophilic cationic palladium(II) complexes containing a diimine ligandwith pendant thienyl groups. X-ray structure of {(PdMe)-Me-II[1,4-bis(2 '-(2-thienyl)ethyl)2,3-dimethyl-1,4-diazabutadiene]}(+)

Authors
Fang, XG Watkin, JG Scott, BL Kubas, GJ
Citation
Xg. Fang et al., Electrophilic cationic palladium(II) complexes containing a diimine ligandwith pendant thienyl groups. X-ray structure of {(PdMe)-Me-II[1,4-bis(2 '-(2-thienyl)ethyl)2,3-dimethyl-1,4-diazabutadiene]}(+), ORGANOMETAL, 20(15), 2001, pp. 3351-3354
Citations number
22
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
ORGANOMETALLICS
ISSN journal
02767333 → ACNP
Volume
20
Issue
15
Year of publication
2001
Pages
3351 - 3354
Database
ISI
SICI code
0276-7333(20010723)20:15<3351:ECPCCA>2.0.ZU;2-F
Abstract
Cationic Pd(II) complexes [(N2S2)Pd(II)Me][BArF] (3) and [(N2S2)Pd(II)][SO3 CF3](2) (7) have been. synthesized by using a new diimine ligand 1,4-bis(2 '-(2-thienyl)ethyl)-2,3-dimethyl-1,4-diazabutadiene (N2S2) that contains se milabile pendant thienyl groups. Both complexes activated the Et3Si-H bond and catalyzed the isomerization of 1-hexene to internal hexenes.