Jd. Beckwith et al., Interaction of the bifunctional Lewis acid 1,2-bis(chloromercurio)tetrafluorobenzene with aldehydes, nitriles, and epoxides, ORGANOMETAL, 20(14), 2001, pp. 3169-3174
The formation of adducts involving the bidentate Lewis acid 1,2-bis(chlorom
ercurio)tetrafluorobenzene (1) and small electron rich organic molecules ha
s been investigated. Compound 1 does not form stable adducts with aliphatic
aldehydes and can be crystallized in base-free form from acetaldehyde. The
X-ray crystal structure of 1 reveals the existence of a highly cross-linke
d supramolecular structure in which the individual molecules are associated
by Hg . . . Cl and Hg . . .F interactions. By contrast, 1 forms an adduct
(2) with benzaldehyde. In this adduct, the benzaldehyde molecule acts as a
terminal ligand and coordinates one of the mercury centers through the form
ation of a long Hg-O bond of 2.68(1) A. The supramolecular structure of 2 i
s that of a layered compound in which the monomers are held by numerous int
ermolecular Hg . . . Cl and Hg . . .F contacts. Arene-fluoroarene interacti
ons are also present and involve the aromatic ring of benzaldehyde, which s
tacks with neighboring tetrafluorophenylene units (centroid distances = 3.5
8 and 3.77 Angstrom). Interestingly, compound 1 forms chelate complexes wit
h acetonitrile (3) and propylene oxide (4). As shown by X-ray single-crysta
l analyses of 3 and 4, the electron rich organic derivatives interact simul
taneously with the two mercury centers via formation of long coordination b
onds (Hg-N = 2.82(1) and 2.93(1) Angstrom in 3; Hg-O =2.71(2) and Hg(2)-0 =
2.77(2) Angstrom in 4). As observed in the structure of 2, compound 3 and
4 form layered solids in which the monomers interact by Hg . . . Cl and Hg
. . .F contacts. Finally, compound 1 readily catalyzes the polymerization o
f propylene sulfide.