Two new coordination host frameworks for the inclusion of 4-amino-benzophenone guest molecules

Authors
Fu, ZY Lin, P Du, WX Chen, L Cui, CP Zhang, WJ Wu, XT
Citation
Zy. Fu et al., Two new coordination host frameworks for the inclusion of 4-amino-benzophenone guest molecules, POLYHEDRON, 20(15-16), 2001, pp. 1925-1931
Citations number
27
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
POLYHEDRON
ISSN journal
02775387 → ACNP
Volume
20
Issue
15-16
Year of publication
2001
Pages
1925 - 1931
Database
ISI
SICI code
0277-5387(20010630)20:15-16<1925:TNCHFF>2.0.ZU;2-V
Abstract
The synthesis and structural characterization of novel organometallic coord ination polymers are reported. The reaction of Cd(NO3)(2) and 4,4'-bipy in CH3OH/H2O gave a 2D coordination network formulated as {[Cd(4,4'-bpy)(2). ( H2O)(2)](NO3)(2). 4H(2)O}(10), which was used to capture an organic guest s pecies (4-amino-benezopheone, C13H11NO (3)) to obtain {[Cd(4,4'-bpy)(2)(NO3 )(H2O)]. NO3. (C13H11NO)(2)} (1). Using L (L = 4,4'-trimethylenedipyridine) instead of 4,4'-bipy, {[Cd(L)(2)(H2O)(2)]. 2H(2)O . 2NO(3).C13H11NO} (2) w as synthesized, which has an interesting cofiguration. (C) 2001 Elsevier Sc ience Ltd. All rights reserved.