On mechanochemically initiated copolymerization of polyvinyl chloride and acrylonitrile by vibromilling

Authors
Gu, AJ
Citation
Aj. Gu, On mechanochemically initiated copolymerization of polyvinyl chloride and acrylonitrile by vibromilling, POLYM-PLAST, 40(2), 2001, pp. 183-194
Citations number
10
Categorie Soggetti
Material Science & Engineering
Journal title
POLYMER-PLASTICS TECHNOLOGY AND ENGINEERING
ISSN journal
03602559 → ACNP
Volume
40
Issue
2
Year of publication
2001
Pages
183 - 194
Database
ISI
SICI code
0360-2559(2001)40:2<183:OMICOP>2.0.ZU;2-L
Abstract
The mechanochemically initiated copolymerization of polyvinyl chloride (PVC ) and acrylonitrile (AN) by vibromilling was studied, investigations were c arried out to determine the effects on copolymerization under mechanical st ress. They included radial acceptor, milling rime, particle size of PVC, an d weight ratios of AN to PVC and balls to reactants. The obtained copolymer was analyzed by FT-IR, turbidimetric titration, and pyrolysis gas chromato graphy (PyGC).