Synthesis and stereochemistry of some new 1,3-dioxane derivatives obtainedfrom 5-aryl-2-furaldehydes

Authors
Grosu, I Balog, M Paisz, C Ple, G Irimie, FD Mager, S Podea, R
Citation
I. Grosu et al., Synthesis and stereochemistry of some new 1,3-dioxane derivatives obtainedfrom 5-aryl-2-furaldehydes, REV RO CHIM, 45(9), 2000, pp. 877-882
Citations number
15
Categorie Soggetti
Chemistry
Journal title
REVUE ROUMAINE DE CHIMIE
ISSN journal
00353930 → ACNP
Volume
45
Issue
9
Year of publication
2000
Pages
877 - 882
Database
ISI
SICI code
0035-3930(200009)45:9<877:SASOSN>2.0.ZU;2-7
Abstract
The NMR investigations on the stereochemistry of some new 1,3-dioxane deriv atives obtained from 5-aryl-2-furaldehydes revealed the anancomeric structu re of the saturated heterocycle in all studied compounds. The free rotation of the furan ring and of its aromatic substituent has been observed even a t low temperature and even if the aromatic substituent was a phenyl ring be aring in ortho position a bulky group (e.g. Iodine).