Reactions of 1,2,4,5-tetrafluoro-3,6-bis(vinylsulfonyl)benzene with nucleophilic reagents containing a mercapto group

Authors
Amosova, SV Gavrilova, GM Gostevskaya, VI
Citation
Sv. Amosova et al., Reactions of 1,2,4,5-tetrafluoro-3,6-bis(vinylsulfonyl)benzene with nucleophilic reagents containing a mercapto group, RUSS J ORG, 37(1), 2001, pp. 93-95
Citations number
4
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
RUSSIAN JOURNAL OF ORGANIC CHEMISTRY
ISSN journal
10704280 → ACNP
Volume
37
Issue
1
Year of publication
2001
Pages
93 - 95
Database
ISI
SICI code
1070-4280(200101)37:1<93:RO1WN>2.0.ZU;2-O
Abstract
Addition of 2-aminoethanethiol and 2-mercaptocthanol at both vinylsulfonyl groups of 1,2,4,5-tetrafluoro-3,6-bis(vinyisulfonyl)benzene occurs through the thiol group of the reagent and yields the corresponding 3,6-dis[2-(2-am inoethylthio)ethylsulfonyl] and 3,6-bis[2-(2-hydroxyethylthio)ethylsulfonyl ] derivatives. The reaction of the title compound with 1,2-ethanedithiol le ads to formation of only polymeric addition products.