Activity of the La1-xSrxMnO3 and La1-xSrxCrO3 phases oxygen isotope exchange and oxidation of CO and CH4

Authors
Mazo, GN Kudryashov, IA Kemnitz, E
Citation
Gn. Mazo et al., Activity of the La1-xSrxMnO3 and La1-xSrxCrO3 phases oxygen isotope exchange and oxidation of CO and CH4, RUSS J PH C, 75(7), 2001, pp. 1113-1119
Citations number
28
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
RUSSIAN JOURNAL OF PHYSICAL CHEMISTRY
ISSN journal
00360244 → ACNP
Volume
75
Issue
7
Year of publication
2001
Pages
1113 - 1119
Database
ISI
SICI code
0036-0244(200107)75:7<1113:AOTLAL>2.0.ZU;2-8
Abstract
Perovskite-like manganites La1-xSrxMnO3 (x = 0, 0.3, 1) and chromites La1-x SrxCrO3 (x = 0, 0.2) were synthesized by the cryochemical method. The tempe rature intervals of predominant occurrence of various oxygen exchange react ions at the complex oxide-gas phase interface were determined by the dynami c-thermal isotope exchange method. The influence of the composition of mang anites and chromites on their catalytic activity in oxygen isotope exchange reactions and the oxidation of carbon monoxide and methane is discussed.