We have demonstrated the feasibility of non-destructively analyzing trace l
evels of water in petroleum-based transmission and hydraulic oils and in a
synthetic polyol ester engine-lubricating oil using photoacoustic spectrosc
opy (PAS) at a wavelength of 2.93 mum. Using the method of standard additio
ns, detection limits of 45, 60, and 515 ppm were obtained for water in the
transmission, hydraulic, and synthetic engine oils, respectively. Lower sen
sitivity for water in the synthetic polyol ester oil was due to a 0.16 mum
shift in the water absorption maximum from the wavelength used for the othe
r oils. A detection limit of 62 ppm was also observed for analysis of water
in standard reference material (SRM) 8507 from the National Institute of S
tandards and Technology (NIST), which is a petroleum oil having a nominal w
ater content of 77 ppm. The results for the petroleum-based oils exceed the
current best detection limits of approximately 100 ppm obtained using Four
ier transform infrared spectroscopy (FTIR) and compare favorably with the d
esired detection limits for water in oil of 10-50 ppm. Factors involved in
implementing this technology in on-line sensors are discussed, (C) 2001 Pub
lished by Elsevier Science B.V.