Synthesis of polydentate ligands containing amides and thiols for biomimetic metal complexes

Authors
Heinrich, L Chottard, JC Li, Y
Citation
L. Heinrich et al., Synthesis of polydentate ligands containing amides and thiols for biomimetic metal complexes, SYN COMMUN, 31(9), 2001, pp. 1323-1333
Citations number
17
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
SYNTHETIC COMMUNICATIONS
ISSN journal
00397911 → ACNP
Volume
31
Issue
9
Year of publication
2001
Pages
1323 - 1333
Database
ISI
SICI code
0039-7911(2001)31:9<1323:SOPLCA>2.0.ZU;2-I
Abstract
Three pentadentate "N2S3'' and one tetradentate "N2S2" new ligands with "N" = CONH and "S" = SH have been synthesized. The key step is the direct diam ide formation from the malonyl diester and the amines in the presence of tr imethylaluminum.