An efficient and selective method for conversion of oximes and semicarbazones to the corresponding carbonyl compounds under solvent-free conditions

Citation
Ar. Hajipour et al., An efficient and selective method for conversion of oximes and semicarbazones to the corresponding carbonyl compounds under solvent-free conditions, SYN COMMUN, 31(8), 2001, pp. 1187-1194
Citations number
33
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
SYNTHETIC COMMUNICATIONS
ISSN journal
00397911 → ACNP
Volume
31
Issue
8
Year of publication
2001
Pages
1187 - 1194
Database
ISI
SICI code
0039-7911(2001)31:8<1187:AEASMF>2.0.ZU;2-I
Abstract
1-Benzyl-4-aza-1-azoniabicyclo[2.2.2]octane dichromate (BAABCD) is a useful reagent for selective conversion of oximes and semicarbazones to the corre sponding carbonyl compounds. The reaction was carried out under solvent-fre e conditions and in the presence of a catalytic amount of aluminum chloride .