Isomer and enantiomer separation of 2-and 4-alkyl-cyclohexanols by stereoselective complex formation with O,O '-dibenzoyl-(2R,3R)-tartaric acid

Authors
Kassai, C Balint, J Juvancz, Z Fogassy, E Kozma, D
Citation
C. Kassai et al., Isomer and enantiomer separation of 2-and 4-alkyl-cyclohexanols by stereoselective complex formation with O,O '-dibenzoyl-(2R,3R)-tartaric acid, SYN COMMUN, 31(11), 2001, pp. 1715-1719
Citations number
8
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
SYNTHETIC COMMUNICATIONS
ISSN journal
00397911 → ACNP
Volume
31
Issue
11
Year of publication
2001
Pages
1715 - 1719
Database
ISI
SICI code
0039-7911(2001)31:11<1715:IAESO2>2.0.ZU;2-8
Abstract
Stereoisomeric mixtures of 2- and 4-alkyl-cyclohexanols form complex with O ,O'-dibenzoyl-(2R,3R)-tartaric acid. The diastereoisomer complex formation can be used for isomer and enatiomer separation as it is trans- and enantio selective in the case of 2-alkyl-cyclohexanols and trans-selective in the c ase of 4-alkyl-cyclohexanols.