Acetylenic silyl ketone as polysynthetic equivalent of useful building blocks in organic synthesis

Authors
Capperucci, A Degl'Innocenti, A Dondoli, P Nocentini, T Reginato, G Ricci, A
Citation
A. Capperucci et al., Acetylenic silyl ketone as polysynthetic equivalent of useful building blocks in organic synthesis, TETRAHEDRON, 57(29), 2001, pp. 6267-6276
Citations number
69
Categorie Soggetti
Chemistry & Analysis","Organic Chemistry/Polymer Science
Journal title
TETRAHEDRON
ISSN journal
00404020 → ACNP
Volume
57
Issue
29
Year of publication
2001
Pages
6267 - 6276
Database
ISI
SICI code
0040-4020(20010716)57:29<6267:ASKAPE>2.0.ZU;2-M
Abstract
Ethynyl silyl ketone 1 proved to be a very efficient Michael acceptor in ca rbocupration and metallocupration reactions. In particular, when using carb ocuprates, a smooth entry to polyenals can be obtained, while, when using m etallocuprates, silyl- and stannylpropenoyl silanes may be obtained, very p owerful intermediates in organic synthesis. (C) 2001 Elsevier Science Ltd. All rights reserved.