Mechanochemical syntheses of bismuth selenides

Citation
E. Klose et R. Blachnik, Mechanochemical syntheses of bismuth selenides, THERMOC ACT, 375(1-2), 2001, pp. 147-152
Citations number
4
Categorie Soggetti
Spectroscopy /Instrumentation/Analytical Sciences
Journal title
THERMOCHIMICA ACTA
ISSN journal
00406031 → ACNP
Volume
375
Issue
1-2
Year of publication
2001
Pages
147 - 152
Database
ISI
SICI code
0040-6031(20010720)375:1-2<147:MSOBS>2.0.ZU;2-4
Abstract
Bi + Se mixtures in the molar ratios of 2:3, 1:1. and 2:1. as well as a Bi + Sb + Se mixture in the molar ratio of 1:1:3 were treated in a planetary b all mill. The compounds Bi2Se3, BiSe, and BiSbSe3 were formed after short m illing periods. The Bi + Se mixture in the molar ratio of 2:1 was less reactive, after 60 m in besides the X-ray reflections of Bi, only few weak lines of an unidentif ied product were observed. (C) 2001 Elsevier Science B.V. All rights reserv ed.