Synthesis and crystal structures of (eta(6)-diarene)Ti-II-bis(tetrachloroaluminate) complexes, diarene = biphenyl or 3,5,3 ',5 '-tetramethyl-biphenyl

Authors
Kupfer, V Thewalt, U
Citation
V. Kupfer et U. Thewalt, Synthesis and crystal structures of (eta(6)-diarene)Ti-II-bis(tetrachloroaluminate) complexes, diarene = biphenyl or 3,5,3 ',5 '-tetramethyl-biphenyl, Z ANORG A C, 627(7), 2001, pp. 1423-1425
Citations number
9
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE
ISSN journal
00442313 → ACNP
Volume
627
Issue
7
Year of publication
2001
Pages
1423 - 1425
Database
ISI
SICI code
0044-2313(200107)627:7<1423:SACSO(>2.0.ZU;2-A
Abstract
Syntheses of (eta (6)-diarene)T-II(AlCl4)(2) complexes were performed by th e Fischer-Hafner method. The diarenes employed were biphenyl and 3,5,3',5'- tetramethyl-biphenyl. In each of the resulting complexes, (eta (6)-C12H10)T i-II(AlCl4)(2) (1) and (eta (6)-C16H18)Ti-II(AlCl4)(2) (2), only one C-6-ri ng of a diarene is coordinatively active. 1: Space group Pbca, Z=8, lattice constants at 20 degreesC: a = 16.864(3), b = 13.931(3), c = 18.807(3) Angs trom; R-1 = 0.048. 2: Space group P2(1)/n, Z= 4, lattice constants at 20 de greesC: a=9.775(1), b=13.720(1), c=20.214(1)Angstrom; beta =95.50(1)degrees ; R-1= 0.050.